Current
Projects
My
research interests fall into the general category of complex
fluids. The systems that I have studied are colloids -- mixtures
of small,
undissolved particles suspended in other surrounding substances.
I have conducted experiments, theoretical work, and computer
simulations on the dynamic and electric properties of colloids
in alternating
electric
fields. The system we are studying is a mixture of small silica
particles in silicone oil. Non-aqueous silica gels, similar to
the ones we have studied, are used widely as "fillers" for
optical-fiber cables. Silica is also the most widely used reinforcement
agent for silicone
rubbers. The interaction between silicone oil and silica, however,
is not well understood on a molecular level.
Students
who have finished two semesters of introductory physics courses
are
encouraged to contact me to arrange for independent studies courses
(PHYS 250/350) or for summer research opportunities related to the following
research projects.
- Gels
and fractals
In the academic year 2003-04, Seila Selimovic ’04 wrote
an honors thesis with me on the aging behavior of silica gels.
We
discovered that mixtures
of silica particles in silicone oil, initially a viscous paste, become
a free-flowing liquid in about 2 weeks of time. We also discovered
that viscoelastic moduli of our samples -- those at different
ages, with different silica concentrations, and with different
kinds of silicone oil -- can be scaled onto a single set of master
curves, showing similarity in the gel network of all of the samples.
Our findings on this aging
behavior have been published in
the Journal of Rheology in 2007. More experiments
are currently being carried out to systematically characterize
how
the viscoelastic
properties
of
silica suspensions
change with time, and
how factors like temperature, silica concentration, and
surfactants affect the aging
behavior.
In
the academic year 2004-05, Paula Popescu ’07
found that the dielectric spectrum of these silica gels changed
little over time, in contrast to the
drastic change in the mechanical properties of the suspensions
over time. This apparent
decoupling between the mechanical properties and the electrical
properties is quite intriguing. Experiments are currently being carried
out
to investigate a possible fractal behavior in the electrical properties
of these gels.
- Electrorheology
When small particles are suspended in an insulating fluid,
the elastic properties of the suspension are very sensitive
to an external electric field applied
to the fluid. Without the field, the fluid flows like a normal
liquid. When a strong
field is applied, the fluid can become very viscous and almost
solid-like. These fluids are called electrorheological
(ER) fluids. In the academic year
2002-2003,
Stella Offner ’03 completed an honors thesis with me on computer simulation
of ER fluids. This work has been published in the journal Physical
Review E.
In Spring 2005, Mona Ali ’06 analyzed the polarization
of particles in alternating electric fields under shear. We are
currently continuing the simulation
work and studying the flow of electrorheological fluids in alternating
electric fields.
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